Abstract. The catalytic decomposition of N2O was studied over Cu-containing zeolites with different Cu loadings and framework topologies (MFI, MOR, FER, BEA, and FAU). The influence of NO, O2, and H2O on the rate of N2O decomposition was investigated in detail. A kinetic model was developed based on the relevant elementary reaction steps in the mechanism of N2O decomposition. The recombinat…
The spatiotemporal resolution and the ever increasing sensitivity of single-molecule fluorescence spectroscopy (SMFS) give access to insights at the molecular level for a wide range of systems, while such details were previously hidden in ensemble-averaged measurements. In particular, SMFS has provided kinetic and molecular understanding in bio- and chemocatalytic processes thanks to the poss…