Tuning the HOMO energy levels in quinoline and biquinoline based donor-accept…

Abstract Four donor-acceptor type polymers based on quinoline and biquinoline have been synthesized by Pd catalyzed direct C-H (hetero)arylation reaction. Polymers P1 and P2 are alternate copolymers of thiophene-benzothiadiazolethiophene (TBTT) unit with quinoline and biquinoline unit, respectively. P3 is a random copolymer containing cyclopentadithiophene (CPDT), benzothiadiazole and quinolin…