Abstract. A novel dispersion polymerization system, with a methanol/water (MeOH/H2O) mixture as reaction medium and a polymerizable dimethylaminomethacrylate methyl chloride (DMC) as stabilizer was developed. By monitoring the polymerization evolution and observing the morphological changes of the polystyrene (PS) particles by SEM, it was found that this system had the following unique feat…