e-journal

Supercritical fluid extraction and on-line hydrodechlorination of chlorinated biphenyls catalyzed by polymer-stabilized palladium nanoparticles

---

Abstract.
Polychlorinated biphenyls spiked in soil can be extracted by a continuous flow supercritical fluid carbon
dioxide system and converted on-line to bicyclohexyl using a polymer-stabilized palladium nanoparticle
catalyst. The catalytic hydrodechlorination of 4-chlorobiphenyl to biphenyl follows a pseudo-first-order
reaction kinetics. The subsequent hydrogenation of biphenyl to bicyclohexyl involves two steps with
cyclohexylbenzene as an intermediate. The hydrogenation reactions also follow pseudo-first-order
kinetics and the rate constants are given in this paper.

Keywords: Polychlorinated biphenyl, Hydrodechlorination, Palladium nanoparticle, Catalysis

---

Ketersediaan

Tidak ada salinan data

Informasi Detail

Judul Seri

Applied Catalysis B: Environmental

No. Panggil

-

Penerbit

London : Elsevier B.V.., 2009

Deskripsi Fisik

Applied Catalysis B: Environmental 88 (2009) 173–179

Bahasa

English

ISBN/ISSN

-

Klasifikasi

-

Tipe Isi

-

Tipe Media

-

Tipe Pembawa

-

Edisi

-

Subjek

KIMIA

Info Detail Spesifik

-

Pernyataan Tanggungjawab

agus

Versi lain/terkait

Lampiran Berkas

Komentar

---

Anda harus masuk sebelum memberikan komentar