e-journal
Thermal and chemical stability of Cu–Zn–Cr-LDHs prepared by accelerated carbonation
Abstract.
Layered double hydroxides CuxZn6 − xCr2(OH)16(CO3)·4H2O with different molar ratios of Cu/Zn/Cr were
synthesized by accelerated carbonation. The products were characterized by XRD, SEM, FT-IR and TG-DTGDSC-
MS. The chemical stability was tested by the modified Toxicity Characteristic Leaching Procedure (TCLP).
The results showed that the products were the mixture of CuxZn6 − xCr2(OH)16(CO3)·4H2O and (CuZn)2(CO3)
(OH)2, with similar thermal behavior. All products were chemically stable with reduced leaching at pH>6
(Cu2+, Zn2+) or >5 (Cr3+).
Keywords: Layered double hydroxides (LDHs), CuxZn6 −xCr2(OH)16(CO3)· 4H2O, Accelerated carbonation, Thermal behavior
Tidak ada salinan data
Tidak tersedia versi lain