e-journal

Fluorocarbon–hydrocarbon incompatibility in micellar polymerizations

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Abstract.
A new approach to micellar polymerization is described. It is well known that hydrocarbons and
fluorocarbons exhibit local phase segregation (demixing) owing to mutual antipathy; here this effect is
employed in monomer swollen micelles with appropriate combinations of hydrocarbon and fluorocarbon
monomers and surfactants. A matrix of these hydro- and fluorocarbon components has been investigated
to delineate the effects of H–F antipathy on the outcomes of polymerization reactions to generate
nanolatices of different size (and possibly morphology). Phase diagrams, 1H NMR and small-angle
neutron (SANS) data have been generated to characterize the systems, indicating new routes to influence
nanolatex formation.

Keywords:
Novel monomer-swollen micelles

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Ketersediaan

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Informasi Detail

Judul Seri

Journal of Colloid and Interface Science

No. Panggil

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Penerbit

London : Elsevier Inc.., 2009

Deskripsi Fisik

Journal of Colloid and Interface Science 330 (2009) 437–442

Bahasa

English

ISBN/ISSN

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Klasifikasi

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Tipe Isi

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Tipe Media

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Tipe Pembawa

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Edisi

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Subjek

KIMIA

Info Detail Spesifik

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Pernyataan Tanggungjawab

agus

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