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e-journal

PTFE/polyamide thin-film composite membranes using PTFE films modified with ethylene diamine polymer and interfacial polymerization: Preparation and pervaporation application

Chung-Hao Yu - Nama Orang; Ying-Ling Liu - Nama Orang; Irdham Kusumawardhana - Nama Orang; Juin-Yih Lai - Nama Orang;

Abstract.
Plasma polymerization of ethylene diamine (EDA) on PTFE film surfaces is applied to modify PTFE surfaces
to become hydrophilic and to incorporate amino groups onto PTFE surfaces. The surface-modified
PTFE films are utilized as substrates for interfacial polymerization of EDA and trimesoyl chloride to prepare
PTFE/polyamide thin-film composite (TFC) membranes. The effect of plasma power for plasma polymerization
on the morphology and performances of the PTFE/PA TFC membranes are examined and discussed. The presence of amino groups on the PTFE substrates provides chemical linkages between PTFE and PA layers in interfacial polymerization to make the PTFE/PA TFC membranes are stable for pervaporation separations. A high permeation flux of 1910 g/h m2 and a separation factor of 290 are observed with the PTFE/PA TFC membranes for pervaporation dehydration on a 70 wt% isopropanol aqueous solution at 70 oC. This approach explores a new method to prepare PTFE-based TFC membranes via interfacial polymerizations. The prepared TFC membranes could be potentially utilized in pervaporation and nanofiltration separations.

Keywords:
Plasma polymerization
Interfacial polymerization
Composite membrane
Poly(tetrafluoroethylene)


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Informasi Detail
Judul Seri
Journal of Colloid and Interface Science
No. Panggil
-
Penerbit
London : Elsevier Inc.., 2009
Deskripsi Fisik
Journal of Colloid and Interface Science 336 (2009) 260–267
Bahasa
English
ISBN/ISSN
-
Klasifikasi
-
Tipe Isi
-
Tipe Media
-
Tipe Pembawa
-
Edisi
-
Subjek
KIMIA
Info Detail Spesifik
-
Pernyataan Tanggungjawab
agus
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Lampiran Berkas
  • PTFE/polyamide thin-film composite membranes using PTFE films modified with ethylene diamine polymer and interfacial polymerization: Preparation and pervaporation application
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