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Octadecyl bonded silica membrane disk modified with Cyanex302 for separation and flame atomic absorption spectrometric determination of nickel from tap water and industrial effluent
Abstract.
A simple and reliable method based upon impregnation of Cyanex302 on octadecyl bonded silica membrane
disk has been developed for separation and atomic absorption spectrometric determination of
nickel. The influence of various parameters like aqueous phase pH, flow rate and volume of eluent were
investigated systematically to optimize the conditions for quantitative sorption and desorption of nickel.
The break through volume for nickel was greater than 1.0dm3, enrichment factor more than 100 and a
detection limit of 2.1 ugdm−3 was achieved. The method applied for detection of nickel in tap water and
effluent sample had a relative standard deviation (R.S.D.) of 0.4%.
Keywords:
Solid phase extraction
Nickel
Cyanex302
Octadecyl bonded silica membrane disk
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