e-journal
Emissions of polycyclic aromatic hydrocarbons from fluidized and fixed bed incinerators disposing petrochemical industrial biological sludge
Abstract.
This study investigated the emissions of polycyclic aromatic hydrocarbons (PAHs) from two fluidized
bed incinerators (FLBI A and FLBI B) and one fixed bed incinerator (FIBI) disposing biological sludge
generated from the petrochemical industries in Taiwan. The results of 21 individual PAHs (including
low (LM-PAHs), middle (MM-PAHs) and high molecular weight PAHs (HM-PAHs)) were reported. The
LM-PAHs mainly dominated the total-PAHs in the stack flue gases, whereas the LM- and HM-PAHs dominated
the total-PAHs in the bottom fly, fly ash and WSB effluent. Due to high carcinogenic potencies
(= total-BaPeq concentrations) in the bottom ash (195 ng g−1) andWSB effluent (20,600 ng L−1) of the FIBI,
cautious should be taken in treating them to avoid second contamination. Lower combustion efficiency
and elevated fuel/feedstock (F/W) ratio for the FIBI led to the highest total emission factor of total-PAHs
(38,400gkg−1). Lower total-PAH removal efficiencies of wet scrubber (WSB) (0.837–5.89%), cyclone
(0.109–0.255%) and electrostatic precipitator (ESP) (0.032%) than those reported elsewhere resulted in
high fraction in PAHcontributions fromthe stack flue gases. Lower total-PAHemission factorwas found for
FLBI A (2380 ugkg−1 biological sludge) with higher combustion efficiency compared to those for FLBI B
(11,500 ugkg−1) and FIBI (38,400 ugkg−1 biological sludge), implying that combustion efficiency plays a
vital role in PAH emissions.
Keywords:
Polycyclic aromatic hydrocarbon
Fluidized bed incinerator
Fixed bed incinerator
Carcinogenic potency
Removal efficiency
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