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A novel and efficient catalytic epoxidation of olefins with adducts derived from methyltrioxorhenium and chiral aliphatic amines

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Abstract.
Nitrogen-based adducts derived from methyltrioxorhenium(VII) and chiral aliphatic amines have been
synthesized and applied to the efficient catalytic epoxidation of olefins with urea hydrogen peroxide
complex as the primary oxidant. These complexes retain their catalytic activity when microencapsulated
in polystyrene. A moderate steroinduction was obtained in the epoxidation of prochiral olefins
with complexes between methyltrioxorhenium and chiral trans-1,2-cyclohexyldiamine. The values of
steroinduction were found to increase after the microencapsulation process.

Keywords:
Catalysis
Methyltrioxorhenium
Chiral amines
Oxidation
Hydrogen peroxide

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Informasi Detail

Judul Seri

Journal of Catalysis

No. Panggil

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Penerbit

London : Elsevier Inc.., 2008

Deskripsi Fisik

Journal of Catalysis 257 (2008) 262–269

Bahasa

English

ISBN/ISSN

00219517

Klasifikasi

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Tipe Isi

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Tipe Media

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Tipe Pembawa

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Edisi

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Subjek

KIMIA

Info Detail Spesifik

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Pernyataan Tanggungjawab

agus

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