e-journal
Nano-TiO2-coated polymer electrolyte membranes for direct methanol fuel cells
Abstract
Composite polymer electrolyte membranes with nano-TiO2 films are fabricated by deposition of titania nanoparticles from a sol solution. Measurements of ion conductivity, methanol permeability and single-cell performance of the modified Nafion membranes are conducted. The TiO2 films adhere well and are crack-free. The protonic conductivity of the composite membranes decreases with increasing titania content, but
methanol permeability is reduced. Preliminary tests on a single-cell of a direct methanol fuel cell (DMFC) indicate that a titania-coated membrane with 0.009 mg cm−2 content gives the highest cell voltage and maximum power density.
Keywords: TiO2 film; Composite membrane; Direct methanol fuel cell; Protonic conductivity; Methanol permeability
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