e-journal
Three dimensional few layer graphene and carbon nanotube foam architectures for high fidelity supercapacitors
Abstract.
Supercapacitors are promising alternative energy storage systems due to their relatively fast
rate of energy storage and delivery. We describe a simple and scalable method to fabricate
three-dimensional (3D) few-layer graphene/multi-walled carbon nanotube (MWNT) hybrid
nanostructures on industrial grade metal foam foils (nickel foam) via a one-step ambient
pressure chemical vapor deposition (APCVD) process. The as-grown few-layer graphene/MWNT
nanocarbon foams are in the form of a homogeneous and densely packed hierarchical
nanostructures and possess a very large surface area of 743 m2 g-1. Symmetrical electrochemical
double-layer capacitors (EDLCs) of 3D hybrid hierarchical few-layer graphene/MWNT
nanostructures show a high specific capacitance of 286 F g-1 which leads to an energy density of
39.72 Wh kg1 and a superior power density of up to 154.67 kW kg1. Moreover, the capacitance
retention of 99.34% after 85000 charge–discharge cycles demonstrates the very high stability of
the electrode architectures for supercapacitors. These merits enable the innovative 3D
hierarchical few-layer graphene/MWNT foam to serve as high performance EDLC electrodes,
resulting in energy storage devices with very high stability and power density.
KEYWORDS: Graphene; Carbon nanotube; Foam; Supercapacitor; Chemical vapor deposition
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