e-journal
Hydrothermal preparation of nitrogen-doped graphene sheets via hexamethylenetetramine for application as supercapacitor electrodes
Abstract.
Nitrogen-doped graphene sheets (NGS) were obtained using a simple hydrothermal reaction with
graphene oxide and hexamethylenetetramine (HMT). HMT plays important roles in both reducing
graphene oxide and doping nitrogen into the graphene sheets. The prepared nitrogen-doped graphene
sheets reduced by hexamethylenetetramine (NGS-HMT) have a high nitrogen (8.62 atom%) content, in
which various nitrogen species, such as pyridinic-N, pyrrolic-N, and quaternary-N, are detected. For
supercapacitor applications, NGS-HMT shows a value of 161 F g−1 at a current density of 0.5 A g−1, and it
also exhibits a high cycle stability.
Keywords: Nitrogen-doped graphene, Hexamethylenetetramine, Supercapacitor
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