e-journal
Electrochemical performance of carbon-coated lithium manganese silicate for asymmetric hybrid supercapacitors
Abstract.
Nanoscale carbon-coated Li2MnSiO4 powder is prepared using a conventional solid-state method and can
be used as the negative electrode in a Li2MnSiO4/activated carbon (AC) hybrid supercapacitor. Carboncoated
Li2MnSiO4 material presents a well-developed orthorhombic crystal structure with a Pmn21 space
group, although there is a small impurity of MnO. The maximum specific capacitance of the Li2MnSiO4/AC
hybrid supercapacitor is 43.2 F g−1 at1mAcm−2 current density. The cell delivers a specific energy as high
as 54Whkg−1 at a specific power of 150Wkg−1 and also exhibits an excellent cycle performance with
more than 99% columbic efficiency and the maintenance of 85% of its initial capacitance after 1000 cycles.
Keywords:
Capacitance
Carbon-coated lithium manganese silicate
Hybrid supercapacitor
Activated carbon
Specific energy
Specific power
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