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e-journal

Polyaniline-deposited porous carbon electrode for supercapacitor

Wei-Chih Chen - Nama Orang; Ten-Chin Wen - Nama Orang; Hsisheng Teng - Nama Orang;

Abstract
Electrodes for supercapacitors were fabricated by depositing polyaniline (PANI) on high surface area carbons. The chemical composition of the PANI-deposited carbon electrode was determined by X-ray photoelectron spectroscopy (XPS). Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) were used to investigate the electrochemical properties of electrodes. An equivalent circuit was proposed to successfully fit the EIS data, and the significant contribution of pseudocapacitance
from PANI was thus identified. A comparative analysis on the electrochemical properties of bare-carbon electrodes was also conducted under similar conditions. The performance of the capacitors equipped with the resulting electrodes in 1 M H2SO4 was evaluated by constant current charge-discharge cycling within a potential range from 0 to 0.6 V. The PANI-deposited electrode exhibits high specific capacitance of 180 F/g, in comparison with a value of 92 F/g for the bare-carbon electrode.

Keywords: Supercapacitor; Double-layer capacitance; Pseudocapacitance; Polyaniline; Porous carbons


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Informasi Detail
Judul Seri
Electrochimica Acta
No. Panggil
-
Penerbit
: Elsevier Science Ltd. All rights reserved., 2002
Deskripsi Fisik
Electrochimica Acta 48 (2003) 641-649
Bahasa
English
ISBN/ISSN
-
Klasifikasi
-
Tipe Isi
-
Tipe Media
-
Tipe Pembawa
-
Edisi
-
Subjek
KIMIA
Info Detail Spesifik
-
Pernyataan Tanggungjawab
yuli/agus
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Tidak tersedia versi lain

Lampiran Berkas
  • Polyaniline-deposited porous carbon electrode for supercapacitor
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