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An investigation of fractal characteristics of mesoporous carbon electrodes with various pore structures

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Abstract
Fractal characteristics of mesoporous carbon electrodes were investigated with various pore structures using the N2 gas adsorption method and the transmission electron microscopy (TEM) image analysis method. The mesoporous carbons with various pore structures were prepared by imprinting mesophase pitch used as a carbonaceous precursor with different colloidal silica particles. All imprinted mesoporous carbons
were composed of two groups of pores produced from the carbonisation of mesophase pitch and from the silica imprinting. The overall surface fractal dimensions of the carbon specimens were determined from the analyses of the N2 gas adsorption isotherms. In order to distinguish the surface fractal dimension of the carbonisation-induced pore surface from that fractal dimension of the silica-imprinted pore surface,
the individual surface fractal dimensions were determined from the image analyses of the TEM images. From the comparison of the overall surface fractal dimension with the individual surface fractal dimensions, it was recognised that the overall surface fractal dimension is crucially influenced by the individual surface fractal dimension of the silica-imprinted pore surface. Moreover, from the fact that the silica-imprinted pore surface with broad relative pore size distribution (PSD) gave lower value of the individual surface fractal dimension than that pore surface with narrow relative PSD, it is concluded that as the silica-imprinted pores comprising the carbon specimen agglomerate, the individual surface
fractal dimension of that pore surface decreases.

Keywords: Surface fractal dimension; Mesoporous carbon electrode; Pore structure; N2 gas adsorption method; Image analysis method

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Ketersediaan

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Informasi Detail

Judul Seri

Electrochimica Acta

No. Panggil

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Penerbit

: Elsevier Ltd. All rights reserved., 2004

Deskripsi Fisik

Electrochimica Acta 49 (2004) 4171–4180

Bahasa

English

ISBN/ISSN

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Klasifikasi

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Tipe Isi

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Tipe Media

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Tipe Pembawa

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Edisi

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Subjek

KIMIA KARBON

Info Detail Spesifik

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Pernyataan Tanggungjawab

yuli/agus

Versi lain/terkait

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