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Effect of annealing temperature on electrochemical characteristics of ruthenium oxide/multi-walled carbon nanotube composites
a b s t r a c t
The preparation and characterization of high-surface-area ruthenium oxide (RuO2)/multi-walled carbon
nanotubes (MWCNTs) composite electrodes for use in supercapacitors is reported in this work. The
RuO2/MWCNTs composites were prepared by the polyol process of RuO2 intoMWCNTsand by Ru annealing
in air before mixed with MWCNTs. The chemically oxidized and annealed Ru nanoparticles contribute
a pseudocapacitance to the electrodes and dramatically improve the energy storage characteristics of the
MWCNTs. These composites annealed at 200 ◦C demonstrate specific capacitances in excess of 130 F/g
in comparison to 80 F/g for pristine MWCNTs. The annealing temperature is found to play an important
role, as it affects the electrochemical performance of annealed RuO2/MWCNTs composites critically due
to its influence on the diffusion of protons into the structure.
Keywords: Annealing, Carbon nanotubes, Ruthenium oxide, Composites, Electrochemical properties
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