e-journal

Study of the nanostructuration capacity of some azopolymers with rigid or flexible chains

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Azobenzene polymers have been the subject of intensive research due to their unique and unexpected properties that allow various applications triggered by light. One of their attractive features is the possibility of changing the orientation of azobenzene chain through trans-cis-trans photoisomerization cycles to photoinduce birefringerence and linear dichroism in thin polymer films. The photochromic behavior and surface structuring capacity of rigid or flexible polymers having side
azobenzene units have been investigated. The polyimides with side azobenzene units have rigid structure, while polysiloxane chains modified with azobenzene groups and nucleobases are considered materials with flexible structure. During the photochromic studies of the investigated polymers, a mechanism concerning the possibility to generate a fluid phase under UV/VIS irradiation was proposed. The photoisomerisation kinetic by UV-Vis irradiation in the solid state compared
with the solution and the cis-trans azobenzene relaxation phenomena were presented. The surface structuring capacity of these polymers was studied using a Nd:YAG laser at 355 nm, at different incident fluencies and pulse numbers.

Keywords Azo-polyimides, structuring, photochromic behavior, thermal stability

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Informasi Detail

Judul Seri

High Performance Polymers

No. Panggil

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Penerbit

: SAGE Publications Ltd., 2012

Deskripsi Fisik

High Performance Polymers 25(1) 13–24 , 2012

Bahasa

English

ISBN/ISSN

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Klasifikasi

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Tipe Isi

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Tipe Media

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Tipe Pembawa

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Edisi

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Subjek

BIOKIMIA

Info Detail Spesifik

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Pernyataan Tanggungjawab

hasnidar/agus

Versi lain/terkait

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