Tailoring Thermotropic Mesophase Morphologies by Molecular Recognition and Fl…

An alkoxyphenyl-substituted melamine derivative has been investigated in binary mixtures with twochain and three-chain semiperfluorinated benzoic acids. Equimolar mixtures of the melamine with the complementary benzoic acids form discrete hydrogen-bonded heterodimers with elongated central core. The dimeric supermolecules involving two-chain partially fluorinated acids organize to infinite b…