Abstract. The origins of the deactivation of a Au/CeO2–Co3O4 catalyst during CO preferential oxidation (PROX) are investigated in detail by means of high-resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), temperature-programmed reduction of hydrogen (H2-TPR), temperature-programmed oxidation of oxygen (O2-TPO), and diffuse …