Abstract. The combined use of chemical analysis, XRD, EPR and Mossbauer techniques provides detailed information on the nature of iron impurities in commercial BEA, MOR and MFI zeolites. EPR and Mo¨ ssbauer spectroscopies evidence that iron impurities are present mainly as tetrahedral Fe(III) species and to a minor extent as octahedral Fe(III) species, with relative amounts depending on th…