Abstract. A detailed kinetic model of NOx storage and reduction, in the presence of H2O and CO2, with hydrogen as the reducing agent was developed and validated in this study. The mechanism was derived from flow reactor experiments conducted at 200–400 ◦C over a Pt/Ba/Al monolith sample. The detailed kinetic model is divided into four sub-models: (i) NO oxidation over Pt, (ii) NOx stora…
Abstract. The influence of the preparation procedure on the performance of NOx storage and reduction catalysts was investigated by means of flow reactor experiments. Three catalysts were examined; one Pt/Al and two Pt/Ba/Al samples. One of the Pt/Ba/Al samples was prepared with Pt impregnated on Al/Ba and one with Ba impregnated on Al/Pt. The results clearly show that the preparation proced…
Abstract. Detailed kinetic modeling was used in combination with flow reactor experiments to investigate the NOx adsorption/desorption and NO oxidation over Cu-ZSM-5. NO oxidation is likely an important step for selective catalytic reduction (SCR) using urea and hydrocarbons, and thus was investigated separately. First the NO2 adsorption on Bro¨ nstedt acid sites in H-ZSM-5 was modeled usi…