Abstract The transesterification of dimethyl oxalate (DMO) with phenol is studied on various Ti-containing phosphate (Ti-P-O) catalysts. The weak acid-base characteristics of Ti-P-O catalysts are responsible for the high activity and selectivity to methyl phenyl oxalate (MPO) and diphenyl oxalate (DPO). Keywords: Transesterification, dimethyl oxalate, methylphenyl oxalate, diphenyl oxalate