Abstract. Dispersed Na0.6CoO2·yH2O and Li0.5CoO2 powders have been obtained at room temperature by rapid precipitation in aqueous solutions of LiOH or NaOH in the presence of a strong oxidizer. The precipitates are well crystallized and consist of nanoscale platelets with high specific area (above 100 m2/g). The Li0.5CoO2 phase is stable in aqueous electrolytes whereas the Na0.6CoO2·yH2O …