Abstract. Formation of polymeric spheres in nanometer to sub-micrometer is achieved through a spin-coating process with polyamide (from 4,4-(hexafluoroisopropylidene)dianiline and 4,4-dicarboxydiphenylether) solutions in N,N-dimethylformamide and N,N-dimethylacetamide. The formation of polymeric spheres and their sizes are dependent on the polymer solution concentrations and the rates in …