Abstract. Na-bentonite was modified by intercalation of poly(dimethyldiallylammonium chloride) (PDMDAAC). The XRD pattern and TEM image indicated that an exfoliated nanocomposite was obtained. Then, graft polymerization of acrylic acid onto starch was carried out to form an amphoteric nanocomposite hydrogels with semi-interpenetrating polymer networks (semi-IPN) in the dispersion of the nan…