Abstract : A new Titanium (IV) complex, dichlorobis (salicylato)titanium(IV) [TiL2Cl2] (1) {LH= Salicylic acid} has been synthesized and characterized by elemental analysis, 1H NMR, 13C NMR, IR and UV-visible spectroscopy. As a post-metallocene complex it’s olefin polymerization activity has been investigated at room temperature in aqueous emulsion. In presence of tetraphenylborate as cocata…