Abstract A comprehensive investigation of polybromodiphenyl ethers (PBDEs) in wastewater was conducted in the second largest international metroplex area along the U.S. and Mexico (MX) border. Concentrations of PBDEs in wastewater and sludge were measured in four wastewater treatment plants (WWTPs) in El Paso, Texas and two WWTPs in Cd. Juarez, Chihuahua, MX. A green approach in sample prepa…