Abstract. High-energy ball milling has been employed to convert a microcrystalline, stoichiometric (S/Mo = 2), catalytically completely inactive MoS2 (prepared by high-temperature decomposition of ammonium tetrathiomolybdate, ATM) into an active catalyst, the activity profile of which was studied with test reactions (ethylene hydrogenation, H2/D2 scrambling, cis–trans isomerization of cis…
Abstract. The preparation, characterization, and catalytic properties of Pd nanoparticles supported on mesoporous organic–inorganic hybrid materials are described for continuous-flow aerobic oxidation of alcohols using supercritical carbon dioxide (scCO2) as a mobile phase. The nanoparticles were generated “bottom-up” from molecular precursors that were precoordinated to the support t…