Abstract. High conductivity and solubility of polypyrrole (PPy)/multi-walled carbon nanotubes (MWCNT) composites has been successfully synthesized by in situ chemical oxidation polymerization using various concentrations of cationic polyelectrolyte poly(styrenesulfonate) (PSS) and ammonium peroxodisulfate (APS). Raman spectroscopy, FTIR, EPR, FESEM and HRTEM were used to characterize their …