Abstract. Three-dimensional (3D) graphene was synthesized by chemical vapour deposition with nickel foam as a substrate. Based on the 3D graphene foams, free-standing grapheneepolyaniline (PANI) hybrids were produced by in-situ polymerization of aniline monomer under acid condition, and characterized by scanning electron microscopy (SEM), Fourier transformation infrared (FTIR), and Raman sp…