Binuclear l-hydroxo-bridged iron clusters derived from surface organometallic…

Abstract. Binuclear iron clusters were constructed successfully in cavities of HY Zeolite by surface organometallic chemistry (SOMC) of ferrocene. UV–visible diffuse reflection (UV–vis DRS), X-ray absorption fine structure (XAFS), electron paramagnetic resonance (EPR), and infrared (IR) spectroscopies were used to characterize the structure of the formed binuclear iron clusters. The res…