Abstract. CdSe and CdSe/CdS core/shell nanoparticles (NPs) were synthesized by using Gemini surfactant, 1,10- bis(a-hexadecyl pyridine) decamethylene dibromide (abbreviated Py-16-10-16), as a soft template. Subsequent analysis revealed that the as-synthesized CdSe NPs and CdSe/CdS core/shell NPs were highly luminescent with quantum yields of 18% and 35%, respectively, compared with Rhodamin…