Abstract. The catalytic activity of Rh/CeO2–ZrO2 for NO reduction by C3H6 under stoichiometric conditions was found to depend strongly on the Ce/Zr composition. Rh/CeO2–ZrO2 with a Ce/Zr molar ratio of 50/50 (Rh/CZ-50/50) had the greatest activity; Ce/Zr = 74/26 (Rh/CZ-74/26), the least. The Rh/CZ-50/50 also showed specifically high intrinsic activity expressed in terms of turnover freq…
Abstract. Delafossite-type CuMO2 (M: trivalent cation) compounds were synthesized and found to exhibit oxygen storage capacity under oxidation/reduction cycle. The oxygen storage capacity values of CuFeO2 and CuMnO2 at lower temperature were larger than those of CuAlO2, CuGaO2- and CeO2-based materials. The large OSC includes an oxygen uptake at low temperature attributed to formation of me…